Product ID:5-9070 METHANOL 4X4L
MSDS Date:05/01/1989
FSC:6810
NIIN:00-098-0149
MSDS Number: BKYGM

J T BAKER INC

222 RED SCHOOL LANE
PHILLIPSBURG, NJ 08865

Emergency Phone: (908) 859-2151

Info Phone: (800) 582-2537

Cage: DO803

LABCO SCIENTIFIC DIV OKLAHOMA CITY OK

PHILLIPSBURG, NJ 08865 US

Telephone: 1-800-582-2537

Cage: 1A109

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 90-100%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:ORAL LD50 (RAT): 5628 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION:
HARMFUL/HEADACHE/NAUSEA/VOMITING/DIZZINESS/NARCOSIS/RESPIRATORY
FAILURE/LOW BLOOD PRESSURE/CNS DEPRESSION/FATAL. SKIN:
IRRITATION/DERMATITIS. EYE: IRRITATION/CORNEAL DAMAGE. INGESTION:
HAR
MFUL/BLINDNESS/HEADACHE/NAUSEA/VOMITING/DIZZINESS/GASTROINTESTINAL
IRRITATION/CNS DEPRESSION/HEARING LOSS/FATAL.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: KIDNEY/LIVER DAMAGE. SKIN:
IRRITATION & DERMATITIS. EYES: IRRITATION & CORNEAL DAMAGE.
INGESTION: HARMFUL, BLINDNESS, HEADACHE, NAUSEA, VOMITING,
DIZZINESS, GASTROINTESTINAL IRRITATION, CN S DEPRESSION, HEARING
LOSS, & FATAL. POISON, CANNOT BE MADE NON-POISONOUS.
Medical Cond Aggravated by Exposure:EYE, SKIN, LIVER OR KIDNEY
DISORDERS.

First Aid:INGESTION: IF CONSCIOUS, DRINK PLENTY OF WATER. INDUCE
VOMITING. INHALATION: REMOVE TO FRESH AIR. GIVE CPR OR OXYGEN IF
NEEDED. SKIN/EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS.
OBTAIN MEDICAL ATTENTION IN ALL CASES. POISON, CANNOT BE MADE
NON-POISONOUS.

Flash Point Method:CC
Flash Point:54F
Lower Limits:6%
Upper Limits:36%
Extinguishing Media:ALCOHOL FOAM, DRY CHEMICAL, OR CO2. WATER MAY BE
INEFFECTIVE. USE WATER SPRAY TO REDUCE VAPORS.
Fire Fighting Procedures:WEAR PROTECTIVE EQUIP & SCBA W/FULL FACEPIECE
OPERATED IN POSITIVE PRESSURE MODE. SAFELY, MOVE CONTAINERS. USE
WATER TO KEEP FIRE EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard:VAPORS MAY FLOW TO IGNITION
SOURCES/FLASHBACK. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE.
BURNS W/CLEAR, ALMOST INVISIBLE FLAME. AUTO-IGNITION TEMP: 867F.

Spill Release Procedures:WEAR PROTECTIVE EQUIP. SHUT OFF IGNITION
SOURCES. SAFELY, STOP LEAK. USE WATER SPRAY TO REDUCE VAPORS. TAKE
UP W/SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL & PLACE INTO
CONTAINER FOR LATER DISPO SAL. FLUSH AREA W/WATER.

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID STORAGE AREA.
BOND/GROUND CONTAINERS WHEN TRANSFERRING LIQUID.
Other Precautions:AVOID CONTACT W/EYES, SKIN, CLOTHING, & BREATHING
VAPORS. KEEP OUT OF REACH OF CHILDREN. DON'T SMOKE. CONTACT
W/STRONG OXIDIZERS MAY CAUSE FIRE.

Respiratory Protection:AT CONCENTRATIONS >200 PPM, USE A SELF-CONTAINED
BREATHING APPARATUS.
Ventilation:PROVIDE GENERAL/LOCAL EXHAUST VENTILATION TO KEEP Protective Gloves:RUBBER
Eye Protection:SAFETY GOGGLES, FACE SHIELD
Other Protective Equipment:UNIFORM, PROTECTIVE SUIT
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health

Boiling Pt:B.P. Text:149F
Melt/Freeze Pt:M.P/F.P Text:-144F
Vapor Pres:96
Vapor Density:1.11
Spec Gravity:0.79
Evaporation Rate & Reference:(BU AC = 1 ): 4.6
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID W/PUNGENT ODOR.
Percent Volatiles by Volume:100%

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ACIDS, ZINC, ALUMINUM, & MAGNESIUM.
Stability Condition to Avoid:HEAT, FLAME, FLARES, SMOKING OR OTHER
SOURCES OF IGNITION.
Hazardous Decomposition Products:CO, CO2, & FORMALDEHYDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: U154. FLAMMABLE
LIQUID. UN1230.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.